The function MapAll was seen as important enough to warrant the short form //@, yet I rarely use it, especially compared to others like /@
I don't use it, but has some fun behavior for Listable functions. For example:
If you want each element in a list to have a function applied to it a number of times depending on its nested depth in the list, I guess this the only time I've seen it used.
SetAttributes[f, Listable]
(f //@ {{a}, {{b}}, c}) // Flatten
{f[f[f[a]]], f[f[f[f[b]]]], f[f[c]]}
Generally though I would imagine you could use ReplaceAll whenever you would use this.