Some time after I posted this question, I found that libpq.5.4.dylib resides in /Library/PostgreSQL/9.1/lib/.
So, I created the following link: lrwxr-xr-x 1 sathishvc admin 43 Jan 28 23:40 /usr/local/lib/libpq.5.4.dylib -> /Library/PostgreSQL/9.1/lib/libpq.5.4.dylib.