I have a need to create a wrapper for a DLL, loading and unloading it as needed (for those interested in the background of this question, see How to work around memory-leaki
First of all, since you are calling it via LoadLibrary, there are no classes here - only functions are exported for public consumption. So your mainClass reference would never work. Let's assume you have a function getVersion that is exported.
I would try the following:
Private Declare Function FreeLibrary Lib "kernel32" (ByVal hLibModule As Long) As Long
Private Declare Function LoadLibrary Lib "kernel32" Alias "LoadLibraryA" (ByVal lpLibFileName As String) As Long
Private Declare Function GetProcAddress Lib "kernel32" (ByVal hModule As Long, ByVal lpProcName As String) As Long
Private Declare Function CallWindowProc Lib "user32" Alias "CallWindowProcA" (ByVal lpPrevWndFunc As Long, ByVal hWnd As Long, ByVal Msg As Any, ByVal wParam As Any, ByVal lParam As Any) As Long
Private Sub Foo
On Error Resume Next
Dim lb As Long, pa As Long
Dim versionString As String
Dim retValue as Long
lb = LoadLibrary("D:\projects\other\VB_DLLs\TestDLL\TestDLL.dll")
'retrieve the address of getVersion'
pa = GetProcAddress(lb, "getVersion")
'Call the getVersion function'
retValue = CallWindowProc (pa, Me.hWnd, "I want my version", ByVal 0&, ByVal 0&)
'release the library'
FreeLibrary lb
End Sub