I want to detect whether the browser is refreshed or not using PHP, and if the browser is refreshed, what particular PHP code should execute.
If you mean that you want to distinguish between when a user first comes to the page from when they reload the page check the referrer. In php it is: $_SERVER["HTTP_REFERER"]. See if it is equal the page your script is running on. It may be the case that the client doesn't provide this information, if that happens you could set a cookie or session variable to track what the last requested page was.