Use Array#uniq:
array_of_hashes = [ {'a' => 1, 'b' => 2 , 'c' => 3} ,
{'a' => 4, 'b' => 5 , 'c' => 3},
{'a' => 6, 'b' => 5 , 'c' => 3} ]
array_of_hashes.map { |h| h['a'] }.uniq # => [1, 4, 6]
array_of_hashes.map { |h| h['b'] }.uniq # => [2, 5]
array_of_hashes.map { |h| h['c'] }.uniq # => [3]