In a fresh VCL application Compile and Build operation produce the same binary and map file (with minor differences at the end of .exe file
What you're seeing is simply an artifact of the built-in make logic of the compiler. When you do a build, it tells the compiler to build all available sources. So Delphi processes each source file and for each unit in the uses lists for which it finds source, it will then build that file. It does this recursively. When you do a compile, only the existing .dcu files are loaded and if they're found to be up-to-date, nothing is done. This can actually lead to a different order in which the units are discovered since each .dcu will effectively "flatten" the uses list. Since the units are discovered and loaded in a different order, they are in-turn, linked in a different order. This is why your map files look so different. Given the same sources, the map file should be the same if you do two builds in a row or two compiles in a row.
Other causes for differences are more mundane and include things like the PE header time stamp, and other bits of padding and alignments.