The title basically says it all.
Suppose I have an element which I want to change color on :hover, but while clicked, I want it to swit
yes this is expected behavior,
lets take a look at another example. just adding two classes,
- item
- item
- item
- item
- item
here the class first also comes together with the class item. but if we declare our css in the wrong order that would not give the wanted behavior
.first { background: blue; }
.item { background: red; }
as you can see, the last matching selector will be used. it is the same as your example, no mather what is more logic, the 2 pseudo-classes are concidered equal, thus the same rules apply the last matching defenition wins.
edit
pseudoclasses are equals, it is the one defined last that wins! here is a jsFiddle that proves my point :link defined after :hover, :link wins (test) so, your statement of :hover overriding :link is wrong, its just the same like with :active, its all about the order.