I have a shared hosting plan with Windows Server 2008 and IIS7.5, and there is Microsoft rewriting module installed and enabled.
To remove the www from a domain and redirect to a "naked domain" you could di it like in the following code snippet:
And the other way around (if you prefer that) to redirect a non-www to one with www:
The redirectType="Permanent" is of course optional but for SEO and most scenarios I would recommend it.
Please see also these SO questions/answers: