I usually ask someone else to take a look at the code. While I'm explaining what the code is supposed to do, I sometimes see the bug just as I talk.
When a bug is a tough one, I sit and work until I figure it out and solve the problem. Interestingly enough, there are times when catching a mysterious bug is more enjoyable than everything running smoothly. And the relief and feeling when a bug is resolved, well, not many other things can beat that (except the obvious ones).