Each to their own, but I tend to follow the same order that the MSDN help follows.
I also don't like to nest classes or enums, instead create separate files for them, that also makes writing unit tests easier (since it's easy to find the associated test file when you need to add/fix/refactor a test).
IMHO the order isn't that important because VS makes it very easy to find all members (especially if you follow the one class/interface/enum per file approach), and Sandcastle will group them if you want to build docs, so I'd be more concerned about giving them meaningful names.
