You're right that in general, libraries cannot make anything possible that isn't already possible.
But the libraries don't have to be written in C++ in order to be usable by a C++ program. Even if they are written in C++, they may internally use other libraries not written in C++. So the fact that C++ didn't provide any way to do it doesn't prevent it from being added, so long as there is some way to do it outside of C++.
At a quite low level, some functions called by C++ (or by C) will be written in assembly, and the assembly contains the required instructions to do whatever isn't possible (or isn't easy) in C++, for example to call a system function. At that point, that system call can do anything your computer is capable of, simply because there's nothing stopping it.
