I was trying to install Sencha Touch SDK tools 2.0.0 but could not run it properly. It created an entry in the $PATH variable. Later I deleted the sencha sdk tools folder b
On MAC OS X Leopard and higher
cd /etc/paths.d
There may be a text file in the above directory that contains the path you are trying to remove.
vim textfile //check and see what is in it when you are done looking type :q
//:q just quits, no saves
If its the one you want to remove do this
rm textfile //remove it, delete it
Here is a link to a site that has more info on it, even though it illustrates 'adding' the path. However, you may gain some insight.