Is it Oracle or MySQL or something they have built themselves?
Spanner is Google's globally distributed relational database management system (RDBMS), the successor to BigTable. Google claims it is not a pure relational system because each table must have a primary key.
Here is the link of the paper.
Spanner is Google's scalable, multi-version, globally-distributed, and synchronously-replicated database. It is the first system to distribute data at global scale and support externally-consistent distributed transactions. This paper describes how Spanner is structured, its feature set, the rationale underlying various design decisions, and a novel time API that exposes clock uncertainty. This API and its implementation are critical to supporting external consistency and a variety of powerful features: non-blocking reads in the past, lock-free read-only transactions, and atomic schema changes, across all of Spanner.
Another database invented by Google is Megastore. Here is the abstract:
Megastore is a storage system developed to meet the requirements of today's interactive online services. Megastore blends the scalability of a NoSQL datastore with the convenience of a traditional RDBMS in a novel way, and provides both strong consistency guarantees and high availability. We provide fully serializable ACID semantics within fine-grained partitions of data. This partitioning allows us to synchronously replicate each write across a wide area network with reasonable latency and support seamless failover between datacenters. This paper describes Megastore's semantics and replication algorithm. It also describes our experience supporting a wide range of Google production services built with Megastore.