I am using Firebird SQL. The below mentioned query returns 4 rows as shown in the figure.
SELECT a.EPS_ID,b.C_NAME,c.AY_YR_NAME,d.S_NAME,e.E_NAME
FROM
Learn to use proper, explicit JOIN syntax.
Your problem is that all unaggregated columns need to be in the GROUP BY:
SELECT a.EPS_ID, MAX(b.C_NAME) AS XT, c.AY_YR_NAME, d.S_NAME, e.E_NAME
FROM TBLEXAMPLANNER_S_MSB a JOIN
TBLCLASS_MSB b
ON a.EPS_CLASS_ID = b.C_ID JOIN
TBLACADEMICYEAR_MSB c
ON a.EPS_SESSION_ID = c.AY_ID JOIN
TBLSUBJECTS_MSB d
ON a.EPS_SUB_ID = d.S_ID JOIN
TBLEXAMTYPE_MSB e
ON a.EPS_PE_ID = e.E_ID
GROUP BY a.EPS_ID, c.AY_YR_NAME, d.S_NAME, e.E_NAME;
Note: I would also recommend that you use table abbreviations for table aliases. So, ep for TBLEXAMPLANNER_S_MSB instead of a. Arbitrary table aliases make the query hard to follow.