When one uses \"ALTER TABLE tab ADD col\", the new column gets added to the end of the table. For example:
TABLE: TAB
COL_1 COL_2 COL_4
ALTER TABLE TAB ADD
I know it's old subject (2009) but maybe it will help someone that still looks for an answer. In MySQL, it works 2 add a column anywhere in the table.
ALTER TABLE `tablename` ADD `column_name1` TEXT NOT NULL AFTER `column_name2`;
This is 2 enter a text column, but u can set whatever properties u want for the new column, just make sure u write them with caps.
I found it with Xampp, MySQL admin, when i used it 2 insert a column in the middle of a MySQL table.
Hope it helps.