Developing a simple web application (Eclipse + JBoss + Apache Tomcat) to generate XML files.
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I'd put them in WEB-INF/classes, or bundle them inside your application.jar which will go inside WEB-INF/lib. Then you can load them from the classpath as explained here and here
Even better, if you use maven, the best practice is to put these type of files inside src/main/resources and then maven will take care of this for you.