I am using Windows Forms. With this code I add items to listView from comboBox.
ListViewItem lvi = new ListViewItem();
You should be using ContainsKey(string key) instead of Contains(ListViewItem item)
var txt = comboBox1.Text;
if (!listView1.Items.ContainsKey(txt))
{
lvi.Text = txt;
// this is the key that ContainsKey uses. you might want to use the value
// of the ComboBox or something else, depending the combobox is freetext
// or regarding your scenario.
lvi.Name = txt;
lvi.SubItems.Add("");
lvi.SubItems.Add("");
lvi.SubItems.Add("");
lvi.SubItems.Add("");
listView1.Items.Add(lvi);
}