In most multi-document editors for windowing environments, Control-TAB will utilize an MRU list to bring the user back to the last visible file. What
In Xcode 3 (or any Mac application) you can use Command-Tilde (⌘~) to switch between open windows.
In Xcode 4 you use ⌘} for next tab and ⌘{ for previous tab - command shift bracket.
As a side note, for some reason Xcode 4 won't let me set the key binding for previous/next tab to the standard Control-Tab. When I try it puts in Command-Control-Tab.