From http://codecorner.galanter.net/2012/06/04/solution-for-operation-is-not-valid-due-to-the-current-state-of-the-object-error/
Issue happens because Microsoft Security Update MS11-100 limits number
of keys in Forms collection during HTTP POST request. To alleviate
this problem you need to increase that number.
This can be done in your application Web.Config in the
section (create the section directly under if it
doesn’t exist). Add 2 lines similar to the lines below to the
section:
The above example set the limit to 2000 keys. This will lift the
limitation and the error should go away.