s1.combine_first(s2)
Out[19]:
s1 s2
first second
bar one 0.039203 0.795963
two 0.454782 -0.222806
baz one 3.101120 -0.645474
two -1.174929 -0.875561
foo one -0.887226 1.078218
two 1.507546 -1.078564
qux one 0.028048 0.042462
two 0.826544 -0.375351
# s2.combine_first(s1)