I know that unit testing is desirable, and I am interested in doing unit testing. The only problem is I have no idea how, or even where to start really. So my question is:
Find-a-bug-write-a-test
The next time you find a bug in your code base, before fixing it, write a test. The test should fail. Then, fix the bug. The test should pass.
If the test doesn't pass, there's either a bug in your test, or a bug in your fix.
A person will never find that bug in your code again. The unit tests will find it (and faster than a person can).
This is definitely a small start, but it gets you into testing. Once you've got the hang of it, you'll probably start writing more tests, and eventually get a knack for how code will fail and which tests you need (for example: a test for every business rule).
Later in your progression you setup a continuous integration server, which makes sure your codebase is always solid.