Python\'s list type has an index(x) method. It takes a single parameter x, and returns the (integer) index of the first item in the list that has the value x.
Basica
[i for i, x in enumerate(my_list) if x != value][0]
If you're not sure whether there's a non-matching item, use this instead:
match = [i for i, x in enumerate(my_list) if x != value]
if match:
i = match[0]
# i is your number.
You can make this even more "functional" with itertools, but you will soon reach the point where a simple for loop is better. Even the above solutions aren't as efficient as a for loop, since they construct a list of all non-matching indices before you pull the one of interest.