I\'m getting:
Warning: ldap_start_tls() [function.ldap-start-tls]: Unable to start TLS: Connect error in /var/www/X.php on line Y
I was able to get this working properly with openldap on Amazon Linux (Elastic Beanstalk PHP 7.0) with MacOS Server 5 LDAP, with TLS set to demand.
in /etc/openldap/ldap.conf:
TLS_REQCERT demand
TLS_CACERT /etc/openldap/certs/yourcacert.pem
(note that if you are not using openldap, the path will be /etc/ldap/certs/yourcacert.pem). This setup did not work until I placed the certificate inside the certs folder; it did not work from any other path.
The certificate to be placed in that path is NOT the TLS certificate of the server. It is the CA (Certificate Authority) certificate of the authority whom issued the server/domain specific TLS certificate. Only the CA certificate placed in that path will allow TLS to work before attempting an LDAP bind in php. Get the CA certificate from your server or download it from the authority's site, they are freely available.
To test if LDAP bind is even working without TLS, set TLS_REQCERT never temporarily (may need to comment # out TLS_CACERT). If you get "Can't connect to LDAP" it is not a TLS error; it simply cannot connect to the server and you likely need to open port 389 (not 636 for TLS).
Remember to restart your Apache server every time you make a change to the config file or certificate.