Update 2019: No IE actually supports WebRTC and no IE ever will. In 5 weeks Microsoft Edge will die and long live Chromium based Edge.
That supports WebRTC.
For now IE doesn't support WebRTC. Moreover, it seems like MS don't plan to implement WebRTC. They announced a new technology called CU-RTC-Web - kinda Microsoft analog of WebRTC.
CU-RTC-WEB: http://html5labs.interoperabilitybridges.com/cu-rtc-web/cu-rtc-web.htm
Expected that this CU-RTC-WEB will be compatible with todays WebRTC.
UPDATED
Some people also report that IE supports WebRTC when using http://www.google.com/chromeframe
UPDATED
Microsoft announced supporting WebRTC in IE: http://blogs.msdn.com/b/ie/archive/2014/10/27/bringing-interoperable-real-time-communications-to-the-web.aspx
UPDATED
While Microsoft will be adding WebRTC in IE, probably in 2015, to which version of IE is left to be seen: https://bloggeek.me/microsoft-browser-webrtc/