=> separates the keys from the values in a hashmap literal. It is not overloadable and not specifically connected to symbols.
A hashmap literal has the form {key1 => value1, key2 => value2, ...}, but when used as the last parameter of a function, you can leave off the curly braces. So when you see a function call like f(:a => 1, :b => 2), f is called with one argument, which is a hashmap that has the keys :a and :b and the values 1 and 2.