Probably scanf is somewhat faster than using streams. Although streams provide a lot of type safety, and do not have to parse format strings at runtime, it usually has an advantage of not requiring excessive memory allocations (this depends on your compiler and runtime). That said, unless performance is your only end goal and you are in the critical path then you should really favour the safer (slower) methods.
There is a very delicious article written here by Herb Sutter
http://www.gotw.ca/publications/mill19.htm
who goes into a lot of detail of the performance of string formatters like sscanf and lexical_cast and what kind of things were making them run slowly or quickly. This is kind of analogous, probably to the kind of things that would affect performance between C style IO and C++ style. The main difference with the formatters tended to be the type safety and the number of memory allocations.