I am evaluating WF for use in line of business applications on the web, and I would love to hear some recent first-hand accounts of this technology.
My main interest
We had a project at work that I was involved in using Workflows. The idea (from management), was that us programmers would write the Workflow Activities along with the "engine" and framework. Then non-programmers would take care of all the rest by compiling their own Workflows into dlls which the engine would automatically load.
Management was sold on this idea of non-programmers using Workflow to help develop software, and it was pretty much a complete waste of time. The problem we were trying to solve with this project was relatively complex and we knew from the very beginning that the software would have to be modified almost constantly (its calculations were dependent on other companies and governements).
The end result was that we were unable to make the Workflow modules generic enough for anyone else to use. So the programmers were the ones who were forced to work with the Workflows, and all the Workflows did was get in our way.