I just installed Xcode version 4.3.1 and I get this error:
libxml / tree.h file not found
I have also installed Xcode 4.2, and
In your question, you have a space between the / and usr. Perhaps this is a typo, but the path is:
/
usr
/usr/include/libxml2
Just confirm that is the path in the target build settings:
You can also verify that the path exists on your file system.