Common Lisp, 141 characters:
(defun c ()
  (format t"Number: ")
  (loop for n = (read) then (if(oddp n)(+ 1 n n n)(/ n 2))
     until (= n 1)
     do (format t"~d -> "n))
  (format t"1~%"))
Test run:
Number: 171
171 -> 514 -> 257 -> 772 -> 386 -> 193 -> 580 -> 290 -> 145 -> 436 ->
218 -> 109 -> 328 -> 164 -> 82 -> 41 -> 124 -> 62 -> 31 -> 94 -> 47 ->
142 -> 71 -> 214 -> 107 -> 322 -> 161 -> 484 -> 242 -> 121 -> 364 ->
182 -> 91 -> 274 -> 137 -> 412 -> 206 -> 103 -> 310 -> 155 -> 466 ->
233 -> 700 -> 350 -> 175 -> 526 -> 263 -> 790 -> 395 -> 1186 -> 593 ->
1780 -> 890 -> 445 -> 1336 -> 668 -> 334 -> 167 -> 502 -> 251 -> 754 ->
377 -> 1132 -> 566 -> 283 -> 850 -> 425 -> 1276 -> 638 -> 319 ->
958 -> 479 -> 1438 -> 719 -> 2158 -> 1079 -> 3238 -> 1619 -> 4858 ->
2429 -> 7288 -> 3644 -> 1822 -> 911 -> 2734 -> 1367 -> 4102 -> 2051 ->
6154 -> 3077 -> 9232 -> 4616 -> 2308 -> 1154 -> 577 -> 1732 -> 866 ->
433 -> 1300 -> 650 -> 325 -> 976 -> 488 -> 244 -> 122 -> 61 -> 184 ->
92 -> 46 -> 23 -> 70 -> 35 -> 106 -> 53 -> 160 -> 80 -> 40 -> 20 ->
10 -> 5 -> 16 -> 8 -> 4 -> 2 -> 1