I was recently asked this question in an interview. Even though I was able to come up the O(n²) solution, the interviewer was obsessed with an O(<
The general solution to this problem is not possible in O(n).
At a minimum you need to sort by appointment start time, which requires O(n log n).
There is an O(n) solution if the list is already sorted. The algorithm basically involves checking whether the next appointment is overlapped by any previous ones. There is a bit of subtlety to this one as you actually need two pointers into the list as you run through it:
O(n) solutions for the unsorted case could only exist if you have other constraints, e.g. a fixed number of appointment timeslots. If this was the case, then you can use HashSets to determine which appointment(s) cover each timeslot, algorithm roughly as follows: