Isn't this the simplest way?
By column name:
In [20]: df = pd.DataFrame({'x' : [1, 2, 3, 4], 'y' : [4, 5, 6, 7]})
In [21]: df
Out[21]:
x y
0 1 4
1 2 5
2 3 6
3 4 7
In [23]: df.x
Out[23]:
0 1
1 2
2 3
3 4
Name: x, dtype: int64
In [24]: type(df.x)
Out[24]:
pandas.core.series.Series