Currently i am working in iPhone app, I have successfully upload iPhone app in itunes connect, noe i got some error in that app and fixed now, then i tried to upload a new b
The other answers are outdated since Apple changed the UI in iTunes Connect. This is how it works now:
Note that the steps are referring to the case when you are submitting a new app version of an app but I imagine the steps are very similar for the case of a new app.