Is a fairly arbitrary decision - non-const references to temporaries are allowed when the temporary is the subject of a method call, for example (e.g. the "swap trick" to free the memory allocated by a vector, std::vector().swap(some_vector);)
Short of giving the temporary a name, I don't think you can.
As far as I'm aware this rule exists in C++0x too (for regular references), but rvalue references specifically exist so you can bind references to temporaries - so changing bootrec_reset to take a File && should make the code legal.