As C# operators e.g. +, +=, == are overridable. It lets me think they are sort of methods, thus wonder if there is a way to call them using reflection, on Int32 for instance
What exactly is it you want to do? Dealing with the various meanings of operators (primitive (mapped to specific IL instructions), custom (mapped to static methods), and lifted (provided as a pattern by the compiler)) makes this painful. If you just want to use the operators, then it is possible to write code that provides operator support via generics. I have some code for this that is freely available in MiscUtil (description and examples).
As an untyped example (an note that this isn't hugely efficient, but works):
object x = 123, y = 345; // now forget that we know that these are ints...
object result = Expression.Lambda>(
Expression.Convert(Expression.Add(
Expression.Constant(x), Expression.Constant(y)),
typeof(object))).Compile()();