I logged into MariaDB/MySQL and entered:
SHOW COLLATION;
I see utf8mb4_unicode_ci and utf8mb4_unicode_520_ci amon
utf8mb4_unicode_ci
utf8mb4_unicode_520_ci
To see a bit more discussion of the actual differences, you can go to https://dev.mysql.com/worklog/task/?id=2673 and click "High Level Architecture".