Using the classic code snippet:
if (x & (x-1)) == 0
If the answer is 1, then it is false and not a power of 2. However, working on 5 (not a power of 2) a
You need refresh yourself on how binary works. 5 is not represented as 0001 1111 (5 bits on), it's represented as 0000 0101 (2^2 + 2^0), and 4 is likewise not 0000 1111 (4 bits on) but rather 0000 0100 (2^2). The numbers you wrote are actually in unary.
Wikipedia, as usual, has a pretty thorough overview.