This would give you midnight on the first Sunday of the week:
DateTime t = DateTime.Now;
t -= new TimeSpan ((int) t.DayOfWeek, t.Hour, t.Minute, t.Second);
This gives you the first Monday at midnight:
DateTime t = DateTime.Now;
t -= new TimeSpan ((int) t.DayOfWeek - 1, t.Hour, t.Minute, t.Second);