I am writing a small test app in C with GCC 4.8.4 pre-installed on my Ubuntu 14.04. And I got confused for the fact that the expression a=(b++); behaves in the
Your expectations are completely unfounded.
Parentheses have no direct effect on the order of execution. They don't introduce sequence points into the expression and thus they don't force any side-effects to materialize earlier than they would've materialized without parentheses.
Moreover, by definition, post-increment expression b++ evaluates to the original value of b. This requirement will remain in place regardless of how many pair of parentheses you add around b++. Even if parentheses somehow "forced" an instant increment, the language would still require (((b++))) to evaluate to the old value of b, meaning that a would still be guaranteed to receive the non-incremented value of b.
Parentheses only affects the syntactic grouping between operators and their operands. For example, in your original expression a = b++ one might immediately ask whether the ++ apples to b alone or to the result of a = b. In your case, by adding the parentheses you simply explicitly forced the ++ operator to apply to (to group with) b operand. However, according to the language syntax (and the operator precedence and associativity derived from it), ++ already applies to b, i.e. unary ++ has higher precedence than binary =. Your parentheses did not change anything, it only reiterated the grouping that was already there implicitly. Hence no change in the behavior.