Personally, I like this approach:
TimeSpan ts = ...;
string.Format("{0:%d}d {0:%h}h {0:%m}m {0:%s}s", ts);
You can make this as custom as you like with no problems:
string.Format("{0:%d}days {0:%h}hours {0:%m}min {0:%s}sec", ts);
string.Format("{0:%d}d {0:%h}h {0:%m}' {0:%s}''", ts);