I know that if you execute GCC as such:
gcc -O3 -O2 foo.c
GCC will use the last optimization flag passed (in this case O2). Ho
Normally later options on the line override ones passed previously, as you mention in your first example. I haven't personally come across any different behaviour for -m or -f flags, but I don't know of a specific reference in the documentation.
Note that some options don't behave this way:
$ gcc example.c -DABC -DABC=12
: warning: "ABC" redefined
: warning: this is the location of the previous definition
So there would need to be a -UABC in between there to shut that warning up.
As an aside, clang is particularly good at solving this problem - it will produce a warning if it ignores a command line option, which can help you out.