You can use a set of tools called TestApi, which is an open-source library to aid unit testing. One of such API is called Visual Verification API, and it does exactly what you need - it can compare two images and tell you if they are equal:
// 1. Capture the actual pixels from a given window
Snapshot actual = Snapshot.FromRectangle(new Rectangle(0, 0, 100, 100));
// 2. Load the reference/master data from a previously saved file
Snapshot expected = Snapshot.FromFile("Expected.png"));
// 3. Compare the actual image with the master image
// This operation creates a difference image. Any regions which are identical in
// the actual and master images appear as black. Areas with significant
// differences are shown in other colors.
Snapshot difference = actual.CompareTo(expected);
// 4. Configure the snapshot verifier - It expects a black image with zero tolerances
SnapshotVerifier v = new SnapshotColorVerifier(Color.Black, new ColorDifference());
// 5. Evaluate the difference image
if (v.Verify(difference) == VerificationResult.Fail)
{
// Log failure, and save the diff file for investigation
actual.ToFile("Actual.png", ImageFormat.Png);
difference.ToFile("Difference.png", ImageFormat.Png);
}