SELECT sum(TotalHoursM) + (TotalHoursT) + (TotalHoursW) + (TotalHoursTH) + (TotalHoursF) AS TOTAL FROM LeaveR
looks like you want to SUM all the columns (I'm not sure where "sum 3 columns" comes from), not just TotalHoursM, so try this:
SELECT SUM( ISNULL(TotalHoursM ,0) + ISNULL(TotalHoursT ,0) + ISNULL(TotalHoursW ,0) + ISNULL(TotalHoursTH ,0) + ISNULL(TotalHoursF ,0) ) AS TOTAL FROM LeaveRequest