Taken from MDN
String literals (denoted by double or single quotes) and strings returned from String calls in a non-constructor context (i.e., witho
The existence of an object has little to do with the actual behaviour of a String in ECMAScript/JavaScript engines as the root scope will simply contain function objects for this. So the charAt(int) function in case of a string literal will be searched and executed.
With a real object you add one more layer where the charAt(int) method also are searched on the object itself before the standard behaviour kicks in (same as above). Apparently there is a surprisingly large amount of work done in this case.
BTW I don't think that primitives are actually converted into Objects but the script engine will simply mark this variable as string type and therefore it can find all provided functions for it so it looks like you invoke an object. Don't forget this is a script runtime which works on different principles than an OO runtime.