I get the following error when I start my asp net mvc 4 application:
Could not load file or assembly \'DotNetOpenAuth.Core, Version=4.0.0.0,
Culture=neutral
I do not have the reputation to comment but I can verify that I had this exact problem and Jack gave the correct solution for me. I had recently pressed Add Service Reference and it broke the program with the above error message.
Deleting the _bin_deployableAssemblies folder, and your application's bin folder and then clean and rebuild your application made it work again.