I have a characteristic value which contains the data for an image. In the peripheral I setup the value like this:
_photoUUID = [CBUUID UUIDWithString:bPhoto
I'm guessing you're bumping up against the 512 byte limit on characteristic length. You'll need to move to subscriptions to characteristics and processing of updates to get around this:
Subscribe to the characteristic by calling -[CBPeripheral setNotifyValue:forCharacteristic] (with YES as the notify value).
In -peripheral:didUpdateValueForCharacteristic:error, every update will either be data to append, or something you choose to use on the peripheral side to indicate end-of-data (I use an empty NSData for this). Update your -peripheral:didUpdateValueForCharacteristic:error code so that:
NSMutableData).-[CBPeripheral setNotifyValue:forCharacteristic] with a notify value of NO.-peripheral:didUpdateNotificationStateForCharacteristic:error: is a good spot to manage the initialization and later use of the sink into which you read chunks. If characteristic.isNotifying is updated to YES, you have a new subscription; if it's updated to NO then you're done reading. At this point, you can use NSKeyedUnarchiver to unarchive the data.
In -[CBMutableCharacteristic initWithType:properties:value:permissions], make sure the properties value includes CBCharacteristicPropertyNotify.
Use -peripheralManager:central:didSubscribeToCharacteristic: to kick off the chunking send of your data, rather than -peripheral:didReceiveReadRequest:result:.
When chunking your data, make sure your chunk size is no larger than central.maximumUpdateValueLength. On iOS7, between an iPad 3 and iPhone 5, I've typically seen 132 bytes. If you're sending to multiple centrals, use the least common value.
You'll want to check the return code of -updateValue:forCharacteristic:onSubscribedCentrals; if underlying queue backs up, this will return NO, and you'll have to wait for a callback on -peripheralManagerIsReadyToUpdateSubscribers: before continuing (this is one of the burrs in an otherwise smooth API, I think). Depending upon how you handle this, you could paint yourself into a corner because:
If you're constructing and sending your chunks on the same queue that the peripheral is using for its operations, AND doing the right thing and checking the return value from -updateValue:forCharacteristic:onSubscribedCentrals:, it's easy to back yourself into a non-obvious deadlock. You'll either want to make sure that you yield the queue after each call to -updateValue:forCharacteristic:onSubscribedCentrals:, perform your chunking loop on a different queue than the peripheral's queue (-updateValue:forCharacteristic:onSubscribedCentrals: will make sure its work is done in the right place). Or you could get fancier; just be mindful of this.
To see this in action, the WWDC 2012 Advanced Core Bluetooth video contains an example (sharing VCards) that covers most of this. It doesn't however, check the return value on the update, so they avoid the pitfalls in #4 altogether.
Hope that helps.