MATLAB, as mentioned by others, is great at matrix manipulation, and was originally built as an extension of the well-known BLAS and LAPACK libraries used for linear algebra. It interfaces well with other languages like Java, and is well favored by engineering and scientific companies for its well developed and documented libraries. From what I know of Python and NumPy, while they share many of the fundamental capabilities of MATLAB, they don't have the full breadth and depth of capabilities with their libraries.
Personally, I use MATLAB because that's what I learned in my internship, that's what I used in grad school, and that's what I used in my first job. I don't have anything against Python (or any other language). It's just what I'm used too.
Also, there is another free version in addition to scilab mentioned by @Jim C from gnu called Octave.
