Provisioning Profiles menu item missing from Xcode 5

Question

After spending a whole day installing a fresh copy of Mac OS X v10.8 (Mountain Lion), Xcode 5, fixing provisioning profiles, certificates, creating new ones,

Answer 1

You can add account in the preference -> Accounts setting.

It seems that you already configure xCode4, then I think you can select your certificates for compiling in project-> Building Setting directly since your certificates are already in your keychain.