I have a table like this
userid visitorid time 1 10 2009-12-23 1 18 2009-12-06 1 18 2009-12-14 1 18
Assuming your table is called Visitors:
Visitors
DELETE v1.* FROM Visitors v1 LEFT JOIN ( SELECT userid, visitorid, MAX(time) AS time FROM Visitors v2 GROUP BY userid, visitorid ) v3 ON v1.userid=v3.userid AND v1.visitorid=v3.visitorid AND v1.time = v3.time WHERE v3.userid IS NULL;