Hi iam write this code
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XmlTextReader read = new XmlTextReader(\"http://msdn.microsoft.com/rss.xml\");
DataSet ds = new DataSet();
In my case this error appeared on WCF client's side. On WCF server's side it was caused by missing SQL SELECT permission on a function -- System.Data.SqlClient.SqlException.
WCF client trying to deserialize a dataset, which was obviously not there, kept displaying "Cannot add a SimpleContent..." error. I would not call it a misleading message, but rather one that must be interpreted properly.