This will work for me.
>>> import pandas as pd
>>> df = pd.DataFrame({'name': ['jon','sam','jane','bob'],
... 'age': [30,25,18,26],
... 'sex':['male','male','female','male']}) >>> df
age name sex
0 30 jon male
1 25 sam male
2 18 jane female
3 26 bob male
>>> df.loc['a']=[45,'dean','male']
>>> df
age name sex
0 30 jon male
1 25 sam male
2 18 jane female
3 26 bob male
a 45 dean male
>>> newIndex=['a']+[ind for ind in df.index if ind!='a']
>>> df=df.reindex(index=newIndex)
>>> df
age name sex
a 45 dean male
0 30 jon male
1 25 sam male
2 18 jane female
3 26 bob male